The compensation effect observed on diffusion constants of tritium for lithium compounds
Journal of Nuclear Materials, 183 (1991) 195-201
Kuniaki Watanabe, Kan Ashida, Masao Matsuyama, Hitoshi Miyake
Hydrogen Isotope Research Center, Toyama University, Gofuku 3190, Toyama 930, Japan
Abstract
Attention has been to several Li-compounds which are expected to be tritium
breeding materials in thermonuclear fusion reactors.
Diffusion constants of tritium for them reported so far by many investigators, however,
differ considerably from each other, even for a given material.
We looked at the diffusion constants of tritium for Li2O, LiX (X=F, Cl, Br, I),
Li-Pb, and LiF-MF2 (M=Be, Pb) and found regularity on the scatters of the diffusion constants.
Namely, there was a linear relation as In(D0) =αEd + β,
where D0 and Ed are the pre-exponential factors and activation energies
for the diffusion constants of hydrogen in relevant materials.
It is a similar phenomenon known as the “compensation effect” in chemical reactions.
In the light of this concept, the scatters of the diffusion constants for a given system could be
interpreted as a consequence of the difference in diffusion channels and/or in free energy change
for tritium capture in relevant materials.